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ClO dimer
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ClO dimer : ウィキペディア英語版
ClO dimer

The ClO dimer, dichlorine dioxide or chlorine peroxide is a molecular compound with formula ClOOCl. It is important in the formation of the ozone hole. ClOOCl catalytically converts ozone into oxygen when it is irradiated by ultraviolet light.〔
==Production==
ClOOCl can be produced by laser or ultraviolet photolysis of the chlorine molecule with ozone.〔 The lasers used to break up the chlorine molecule into atoms can be an excimer laser at 248, 308, or 352 nm wavelength. Difluorodichloromethane (CF2Cl2) can also act as a source of chlorine atoms for the formation of the peroxide.〔 Microwave discharge can also break up chlorine molecules into atoms that react with ozone to make chlorine peroxide.〔
:Cl2 + ''h''ν 2Cl
:Cl + O3 O2 + ClO·
:2ClO· + M ClOOCl + M
:ClOOCl + ''h''ν Cl + ClO2
:ClO2 + M Cl + O2

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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